1) 6FeSO4 + 2K2Cr2O7 + 3HNO2 + 8H2O = Cr2(SO4)3 + Cr(NO3)3 + [CrOH]SO4 + 2K2SO4 + 6Fe(OH)3:
2Cr+6 +6e- = 2Cr3+ | 6 | 12 | 2 |
2Fe2+ -2e- = 2Fe3+
N+3 -2e- = N+5 | 4 | | 3 |;
2) Br2 + SnCl2 = SnCl2Br2:
Sn+2 -2e- = Sn+4 | 2 | 2 | 1 |
Br2 +2e- = 2Br- | 2 | | 1 |;
3) NaNO2 + H2O2 = NaNO3 + H2O:
N+3 -2e- = N+5 | 2 | 2 | 1 |
(O2)-2 +2e- = 2(O)-2 | 2 | | 1 |;
4) K2Cr2O7 + 3H2O2 + 8HNO3 = 2KNO3 + 2Cr(NO3)3 + 3O2 + 7H2O:
2Cr+6 +6e- = 2Cr3+ | 6 | 6 | 1 |
(O2)-2 -2e- = O2 | 2 | | 3 |;
5) 2H2O2 + 2KI + HNO2 = I2 + KNO3 + KOH + 2H2O:
(O2)-2 +2e- = 2(O)-2 | 2 | 4 | 2 |
2I- -2e- = I2
N+3 -2e- = N+5 | 4 | | 1 |.